Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6616532 | Electrochimica Acta | 2013 | 34 Pages |
Abstract
A facile reflux method has been developed to prepare porous NiO samples using NaBH4-EG and NaOH-EG as alkaline precipitants, respectively. NaBH4-EG is used as alkaline precipitant for the first time. Precipitants influence the morphology and structure of NiO significantly, further affect their specific capacitances as supercapacitor electrodes. Compared with NaOH, NaBH4-EG as alkaline precipitant shows great superiority on morphology control. NiO synthesized by NaBH4-EG presents spherical spongy shape with high specific surface areas, whereas the sample synthesized by NaOH-EG exhibits agglomerated irregular structure. When being applied as supercapacitor electrodes, the former NiO could achieve an extremely high specific capacitance of 930Â FÂ gâ1 at a current density of 15Â AÂ gâ1, significantly higher than that of the latter one (510Â FÂ gâ1). Moreover, the specific capacitance of the former is as high as 1396Â FÂ gâ1 after 1000-cycle at 4Â AÂ gâ1, revealing superb electrochemical characteristics. The impedance measurement discloses that the electrode prepared by the former NiO possesses lower charge-transfer resistance and ion-diffusion resistance, demonstrating the superiority of NaBH4-EG as alkaline precipitant. NaBH4-EG is an excellent precipitant for the synthesis of porous NiO as supercapacitor electrodes.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Miaomiao Liu, Jie Chang, Jing Sun, Lian Gao,