| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 66173 | Journal of Molecular Catalysis A: Chemical | 2012 | 6 Pages |
Silicadiphenyl phosphinite (SDPP) as a new phosphorylated silica and catalytic amounts of Pd(II) generates nano SDPP/Pd(0) catalyst for the efficient aminocarbonylation of aryl halides in the presence of POCl3 and N,N-dimethylformamide (DMF). Amides are obtained in high yields from aryl iodides and also activated aryl bromides, chlorides.
Graphical abstractSilicadiphenyl phosphinite (SDPP) as a new phosphorylated silica and catalytic amounts of Pd(II) generates nano SDPP/Pd(0) catalyst for the efficient aminocarbonylation of aryl halides in the presence of POCl3 and N,N-dimethylformamide (DMF).Figure optionsDownload full-size imageDownload high-quality image (144 K)Download as PowerPoint slideHighlights► Silicaphosphinite and Pd(II) act as an efficient catalyst for the amidation. ► Amides are obtained in high yields from aryl halides by using of POCl3 and DMF. ► The use of combination of POCl3 and DMF is as an easy approach for amide synthesis.
