Article ID Journal Published Year Pages File Type
6618220 Electrochimica Acta 2013 6 Pages PDF
Abstract
► Mechanistic insights of the electro-induced Stevens rearrangement are provided. ► The reduction of PhCOCH2N+(CH3)2CH2Ph is ascribed to a one-electron transfer process. ► An electrogenerated ammonium ylide has been detected by UV-spectroelectrochemistry.
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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Preview
Detection of an ylide intermediate in the electrochemically-induced Stevens rearrangement of an ammonium salt by in situ UV-vis spectroelectrochemistry
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