Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6619084 | Fluid Phase Equilibria | 2018 | 25 Pages |
Abstract
A thermodynamic study of three ethanolamines, 2-(diethylamino)ethanol, 2-(ethylamino)ethanol and 2-(isopropylamino)ethanol, reporting the measurements of vapor pressure, liquid phase heat capacities, and phase behavior is presented in this work. The vapor pressures were measured using a static method in the temperature interval 238-343â¯K. After a critical assessment of literature data, selected experimental data were correlated using the Cox equation. The liquid phase heat capacities were measured in the temperature range 265-355â¯K using Tian-Calvet calorimetry and the phase behavior was investigated using differential scanning calorimetry (DSC) starting from 183â¯K. For 2-(ethylamino)ethanol and 2-(isopropylamino)ethanol, two monotropically related crystalline forms were identified. To our knowledge, vapor pressure and heat capacity for 2-(isopropylamino)ethanol and phase behavior data for 2-(ethylamino)ethanol and 2-(isopropylamino)ethanol are reported for the first time in this work.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Bruna P. Soares, VojtÄch Å tejfa, Olga Ferreira, Simão P. Pinho, KvÄtoslav RůžiÄka, Michal Fulem,