Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6633012 | Fuel | 2016 | 10 Pages |
Abstract
The effects of CO2 atmosphere on the distribution of volatile organic sulphur compounds during coal pyrolysis and the effect of kaolin addition were studied. Sulphur compounds release was determined by atmospheric pressure-temperature programmed reduction “on-line” coupled with MS (AP-TPR/MS) and “off-line” coupled with GC/MS after thermal desorption (AP-TPR-TD-GC/MS). The results show that thiophene and methyl and ethyl substituted analogues were released between 400 and 500 °C, while relatively more complex organic sulphur compounds such as benzothiophene and methyl benzothiophene evolved at higher temperature. In CO2, thiophenes evolved at lower temperature due to its more reactive and oxidative character. With kaolin addition, an increase in most registered volatile organic sulphur compound amounts was noticed both in inert and CO2 gas, due to the catalytic effect of kaolin.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Ying Gu, Jan Yperman, Guy Reggers, Robert Carleer, Jens Vandewijngaarden,