| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 66349 | Journal of Molecular Catalysis A: Chemical | 2011 | 9 Pages |
A new palladium grafted mesoporous organic polymer catalyst has been synthesized through the reaction of palladium(II) acetate with mesoporous poly-triallylamine (MPTA-1) in methanol. Powder XRD, HR TEM, FE SEM-EDS, AAS, UV–vis spectroscopic tools are employed to characterize this supported palladium catalyst Pd–MPTA-1. The Heck coupling reactions between a series of aryl halides and alkenes have afforded the corresponding C–C coupling products in good yield over this Pd-catalyst using water as reaction medium. This protocol provides a simple strategy for the generation of a variety of new C–C bonds by using this recyclable heterogeneous catalyst under environmentally benign conditions.
Graphical abstractAn aqueous phase Heck coupling reaction between a series of aryl halides and alkenes has been afforded good yield to the corresponding C–C coupling products using a new mesoporous organic polymer supported palladium catalyst under environmentally benign conditions.Figure optionsDownload full-size imageDownload high-quality image (194 K)Download as PowerPoint slideHighlights► Pd-grafted functionalized mesoporous polymer nanoparticles. ► Heck coupling over heterogeneous catalyst. ► Water as solvent. ► C–C bond formation.
