Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6642847 | Fuel | 2013 | 7 Pages |
Abstract
⺠The formation of the tetrahedral intermediate is the rate determining step. ⺠With counter-ion the gas-phase reaction proceeds through a concerted mechanism. ⺠In solution the reaction proceeds through a stepwise mechanism for the EtOK attack. ⺠Activation free energies were basically independent of the length of the side chain.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Augusto Cesar Huppes da Silva, Sebastião Claudino da Silva, Evandro L. Dall'Oglio, Paulo T. Jr., Carlos Alberto Kuhnen,