Article ID Journal Published Year Pages File Type
66548 Journal of Molecular Catalysis A: Chemical 2010 7 Pages PDF
Abstract

Iron containing cubic mesoporous MCM-48 materials were prepared by a modified Stöber synthesis method. These materials were characterized by powder X-ray diffraction (XRD), nitrogen isotherms, diffuse-reflectance UV–Vis spectroscopy, and electron microscopy. These materials exhibited high catalytic activity towards the Baeyer–Villiger oxidation of cyclic ketones using benzaldehyde and molecular oxygen. The Fe-MCM-48 mesoporous materials showed excellent recyclability and the integrity of the cubic phase was preserved after the catalytic activity.

Graphical abstractFe-MCM-48 mesoporous materials were prepared at room temperature and characterized by a variety of techniques. These materials exhibited high catalytic activity towards the Baeyer–Villiger oxidation of cyclic ketones.Figure optionsDownload full-size imageDownload high-quality image (323 K)Download as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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