Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6659719 | The Journal of Chemical Thermodynamics | 2018 | 21 Pages |
Abstract
In the present work, we report the standard combustion energies of 2-mercapto-1-methylimidazole, 2-mercapto-5-aminobenzimidazole and 2-mercapto-5-methoxybenzimidazole, obtained experimentally from measurements with a rotatory-bomb combustion calorimeter. With these data, for each one of the three aforementioned compounds, the corresponding standard molar combustion enthalpies and the standard molar enthalpies of formation, in the crystalline phase, are calculated. The enthalpies of sublimation of each compound, obtained experimentally using a Calvet Setaram HT 1000â¯microcalorimeter, are also reported. Using the values of the enthalpies of formation in the crystalline phase and the enthalpies of sublimation, both at 298.15â¯K, for each compound, the corresponding standard molar enthalpies of formation in gas phase were calculated. Complementary, the enthalpies of formation in the gaseous phase were derived from theoretical calculations made with Gaussian-n composite methodology with nâ¯=â¯3 and 4. The experimental and computational studies suggest that in gaseous phase, the form more stable of each compound is the thione form.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Gastón Perdomo, Henoc Flores, Fernando Ramos, Rafael Notario, Vera L.S. Freitas, Maria D.M.C. Ribeiro da Silva, E. Adriana Camarillo, Juan Z. Dávalos,