Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6659843 | The Journal of Chemical Thermodynamics | 2018 | 38 Pages |
Abstract
In this article the volumetric behaviour of the nanostructured liquids, butyltrimethylammonium bis(trifluoromethylsulfonyl)imide and 1-butyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide, is reported. Density was measured in the temperature range (278.15-398.15)â¯K up to 120â¯MPa with a high pressure densimeter based on the vibrating tube principle. Experimental densities were correlated as a function of temperature and pressure by means of the Tammann-Tait equation obtaining standard deviations lower than 3.5â¯Ãâ¯10â4â¯g·cmâ3. In addition, the isobaric thermal expansivity and the isothermal compressibility have been calculated from the Tait-like correlation. Furthermore, two group contribution methods proposed by Gardas and Coutinho and by Jacquemin et al. were applied to these fluids to analyse their prediction abilities for the high-pressure density.
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Authors
Mohamed Dakkach, Félix M. Gaciño, Sofia K. Mylona, MarÃa J.P. Comuñas, Marc J. Assael, Josefa Fernández,