Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6660012 | The Journal of Chemical Thermodynamics | 2016 | 4 Pages |
Abstract
A pure zinc borate, Zn[B12O14(OH)10], has been synthesized and characterized by XRD, FT-IR, simultaneous TG-DTA techniques, and chemical analysis. The molar enthalpy of solution of Zn[B12O14(OH)10] (s) in 1 mol·dmâ3 HCl(aq) was measured by microcalorimeter at T = 298.15 K. The molar enthalpy of solution of ZnO(s) in the mixture solvent of 2.00 cm3 of 1 mol·dmâ3 HCl(aq) and calculated amount of H3BO3 was also measured. With the incorporation of the previously determined enthalpy of solution of H3BO3(s) in 1 mol·dmâ3 HCl(aq), together with the use of the standard molar enthalpies of formation for ZnO(s), H3BO3(s), and H2O(l), the standard molar enthalpy of formation of â(9646.6 ± 9.6) kJ·molâ1 at T = 298.15 K was obtained on the basis of an appropriate thermochemical cycle. In addition, the molar enthalpy of formation of â9492.7 kJ·molâ1 for [B12O14(OH)10]2â has also been estimated by a group contribution method, which has been used to predict the ÎfHmθ of a series of transition metal borates of M[B12O14(OH)10] (MII = Mn, Zn, Fe, Co, Ni). These estimated data have been used to further compare the stability of this series of transition metal borates.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Pan Liang, Jie Wang, Zhi-Hong Liu,