Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6660512 | The Journal of Chemical Thermodynamics | 2015 | 27 Pages |
Abstract
The (liquid + liquid) solubility curves have been determined by a synthetic method for six binary mixtures of [acetonitrile + {heptyl methyl ether CH3OnC7H15, or ethyl hexyl ether C2H5OnC6H13, or pentyl propyl ether nC3H7OnC5H11, or isopentyl propyl ether nC3H7Oi C5H11, or dibutyl ether nC4H9OnC4H9, or butyl isobutyl ether nC4H9OiC4H9}]. The possibility of the COSMO-SAC model to account for the thermodynamic differences between these systems has been tested and the discussion on the influence of screening charge of ethers on the system properties was undertaken.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Mateusz Reda, Åukasz RuszczyÅski, Marek GliÅski, Tadeusz Hofman,