Article ID Journal Published Year Pages File Type
6660697 The Journal of Chemical Thermodynamics 2015 4 Pages PDF
Abstract
Experimentally determined volumetric properties of the liquid binary mixture of {water (1) + glycerol (2)} were processed to calculate the changes of the following thermodynamic parameters with pressure: excess molar Gibbs free energy, ΔPo→PGmE, excess molar entropy, ΔPo→PSmE, excess molar enthalpy, ΔPo→PHmE, as well as the enthalpy of mixing of water and glycerol, HmE, at 100 MPa. The mixing enthalpies of water and glycerol, HmE, became more exothermic with pressure increasing at all temperatures studied.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, ,