Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6662851 | Journal of Electroanalytical Chemistry | 2013 | 12 Pages |
Abstract
New sodium and chloride ion-selective membrane cocktails for glass-capillary microelectrodes were developed satisfying the demands for corrosion studies. Membrane cocktails were optimized to provide a wide pH working range, good long-term stability and reproducibility of potential. The proposed sodium-selective cocktail contains sodium ionophore VI, potassium tetrakis(4-chlorophenyl) borate and 2-nitrophenyl octyl ether. The chloride-selective cocktail consists of tridodecylmethylammonium chloride and 2-nitrophenyl octyl ether. The proposed microelectrodes were successfully applied to measure the concentration of Clâ and Na+ over corroding cut-edge samples of metallic coated steel and can be recommended for measuring the distribution of Na+ and Clâ in corrosion applications.
Related Topics
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Chemical Engineering
Chemical Engineering (General)
Authors
Valentine A. Nazarov, Maryna G. Taryba, Elena A. Zdrachek, Kseniya A. Andronchyk, Vladimir V. Egorov, Svetlana V. Lamaka,