Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6663085 | Journal of Electroanalytical Chemistry | 2013 | 7 Pages |
Abstract
As shown in the literature, many methods have been developed to improve signals, reproducibility and stabilities of surface-enhanced Raman scattering (SERS) for their reliable applications. However, the fabrication can be laborious. In this work, we propose a simple pathway to prepare SERS-active substrates with Al2O3-modified Au nanoparticles (NPs) by sonoelectrochemical deposition-dissolution cycles (SEDDCs). Based on probe molecules of Rhodamine 6G (R6G), an enhancement factor of 4.4 Ã 108 and a detection limit of 2 Ã 10â14 M were observed on the proposed SERS-active substrates. The reproducibility and stabilities of the proposed SERS-active substrates are satisfactory. Also, the prepared Al2O3-modified Au NPs-deposited substrate can markedly improve the thermal stability by raising the operation temperature over 50 °C, as compared with unmodified Au NPs-deposited substrate. Meanwhile, aging of SERS effect observed on this proposed substrate is slight in an atmosphere of 50% RH and 20% (v/v) O2 at 30 °C for 60 day.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Chun-Chao Chang, Chung-Chin Yu, Yu-Chuan Liu, Kuang-Hsuan Yang,