A new modeling method for determining electrochemical parameters from LSV experiments using the stochastic noise. Part I: Theory and validation

Article ID	Journal	Published Year	Pages	File Type
6663220	Journal of Electroanalytical Chemistry	2013	9 Pages	PDF

Abstract

âº We propose a new modeling procedure for the kinetics of electrochemical reactions. âº The local polynomial model is applied to one polarization curve. âº The analytical fitting provides the model parameters and their uncertainty. âº The local polynomial model is developed and validated on synthetic data. âº We provide guidelines on how to use the modeling procedure on LSV experiments.

Keywords

Parameter fitting Local polynomial approximation Electrochemical modeling Stochastic noise Linear sweep voltammetry