Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6663379 | Journal of Electroanalytical Chemistry | 2012 | 10 Pages |
Abstract
⺠Asymmetric Marcus-Hush (MH) model is employed in variable temperature voltammetry. ⺠The reorganization energy and degree of adiabaticity can be quantified. ⺠Reduction of nitropentane in acetonitrile is studied via fast-scan cyclic voltammetry. ⺠A reorganization energy of 1.7 eV and a symmetry parameter of â0.14 are obtained. ⺠Asymmetric MH model and Butler-Volmer lead to superior fitting than symmetric MH.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Danu Suwatchara, Neil V. Rees, Martin C. Henstridge, Eduardo Laborda, Richard G. Compton,