| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6663471 | Journal of Electroanalytical Chemistry | 2012 | 7 Pages |
Abstract
⺠Nonlinear solvation effects on electrode kinetics are examined using Matyushov model. ⺠Different solvent force constants in the oxidized and reduced forms are considered. ⺠Nonlinear solvation leads to curved, asymmetric Tafel and curved Randles-Sevcik plots. ⺠The evaluation of these effects is possible from Butler-Volmer transfer coefficient. ⺠Cyclic voltammetry of diffusional and surface-attached redox couples is analyzed.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Eduardo Laborda, Martin C. Henstridge, Richard G. Compton,