| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6663527 | Journal of Electroanalytical Chemistry | 2012 | 7 Pages |
Abstract
⺠Asymmetric Marcus-Hush model is applied to surface-bound redox systems. ⺠Asymmetric model offers additional physical insight into electron transfer processes. ⺠The model accounts for asymmetric, curved Tafel plots reported in literature. ⺠Peak current and potential behaviours in CV and SWV are satisfactorily described. ⺠For finite kinetic redox systems the asymmetric model is recommended.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Martin C. Henstridge, Eduardo Laborda, Richard G. Compton,