Article ID Journal Published Year Pages File Type
6663603 Journal of Electroanalytical Chemistry 2011 6 Pages PDF
Abstract
► Hydrogen evolution reaction on gold displays two Tafel slopes of 0.06 V and 0.12 V. ► Kinetic dependences on solution composition evidence the barrierless discharge. ► The alternative explanations of the low Tafel slope are shown to be incorrect. ► The barrierless discharge is described in terms of the quantum-mechanical theory.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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