| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6663605 | Journal of Electroanalytical Chemistry | 2011 | 4 Pages |
Abstract
⺠The electron transfer system considered is the oxidation of ferrocene. ⺠The parameters estimated include the outer sphere Gibbs activation energy for electron transfer, the longitudinal relaxation time, and the standard rate constant. ⺠The longitudinal relaxation time increases with increase in the length of the alkyl chain. ⺠As a result the standard rate constant for oxidation of ferrocene decreases as the cation in the ionic liquid is made longer.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
W. Ronald Fawcett, Attila Gaál, Daniel Misicak,