| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6663607 | Journal of Electroanalytical Chemistry | 2011 | 9 Pages |
Abstract
⺠We studied intramolecular dissociative electron transfers (DETs). ⺠The systems were trans(cyclohexane) axial(benzoyloxy)-axial(bromide) molecules. ⺠DET rates were 1.1 orders of magnitude faster than for the cis equatorial, axial isomers. ⺠The results are discussed in the framework of the German-Kuznetsov DET theory. ⺠The outcome is compared with that of other nonadiabatic intramolecular DETs.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Sabrina Antonello, Alfonso Venzo, Flavio Maran,