| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6671480 | The Journal of Supercritical Fluids | 2012 | 9 Pages |
Abstract
⺠Methylation of indole in supercritical methanol catalyzed by TMOS and TEOS at 350 °C. ⺠Selectivity on skatole formation (3-MI) was 95-96 mol% with using catalyst. ⺠Combination of TMOS-methanol is real methylating system. ⺠Water content influences on indole conversion and regioselectivity of methylation. ⺠No reaction was observed in sc-ethanol or sc-isopropanol with and without catalyst.
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Authors
I.V. Kozhevnikov, A.L. Nuzhdin, G.A. Bukhtiyarova, O.N. Martyanov, A.M. Chibiryaev,