Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6714672 | Construction and Building Materials | 2018 | 7 Pages |
Abstract
This study investigated the effect of nano-silica on the hydration and conversion of calcium aluminate cement (CAC). The specimens were exposed to 60â¯Â°C to accelerate the transformation of hydrates in CAC after initial curing at 20â¯Â°C. At an early stage of curing, adding nano-silica in CAC mitigated the formation of C3AH6 and AH3. At 1â¯day after exposure to 60â¯Â°C, the compressive strength reduction was observed in all specimens, and it was closely related to the conversion of CAH10. That is, the conversion of all specimens occurred at 28â¯days after exposure, which resulted in a reduction in compressive strength. However, adding nano-silica mitigated the conversion from metastable phases (CAH10 and C2AH8) to stable phases (C3AH6 and AH3). As a result, the extent of compressive strength loss could be reduced by the formation of strätlingite (C2ASH8) in the case of 4% addition of nano-silica. In conclusion, adding nano-silica in CAC was effective regarding structural integrity by delaying the conversion of metastable hydrates, as well as maintaining the long-term strength of CAC by forming strätlingite.
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Authors
H.M. Son, S.M. Park, J.G. Jang, H.K. Lee,