| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67159 | Journal of Molecular Catalysis A: Chemical | 2009 | 9 Pages |
Abstract
The oxidative carbonylation of benzotrifluoride to form trifluoromethylbenzoic acid (TFMBA) has been catalyzed using either Rh(III) or a Pd(II) cation in combination with a carboxylic acid and its anhydride, ammonium metavanadate, CO, and O2. The influence of metal cation and vanadate concentrations, temperature, time, acid composition, and gas pressures, were explored.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Joseph Zakzeski, Alexis T. Bell,