Article ID Journal Published Year Pages File Type
672728 Thermochimica Acta 2016 7 Pages PDF
Abstract

•Wood viscoelasticity were examined during adsorption processes under hygrothermal conditions.•Comparison of viscoelasticity under static and dynamic loadings was investigated.•Mechano-sorptive effect could be detected under dynamic loading.•Mechano-sorptive effect was more pronounced at varied humidity than constant.

The viscoelasticity of Chinese fir (Cunninghamia lanceolata [Lamb.] Hook.) was examined during moisture adsorption at a relative humidity step (RHstep) mode (made up of RHramp and RHisohume periods) from 0 to 90% RH and temperatures ranging from 30 to 80 °C. The viscoelastic tests were carried out by static and dynamic loadings. The moisture adsorption resulted in an increase in compliance or damping. The phenomena that more pronounced mechano-sorptive (MS) effect during RHramp periods than RHisohume periods were observed, indicating that the MS effect could be detected by both static and dynamic loading tests. At 70 or 80 °C dynamic loading tests, the lignin transition was observed. Before the occurrence of the lignin transition, or when temperature at or below 60 °C, a smooth master curve of E″ vs. E′ was formed and indicated that during the adsorption process the temperature not only accelerated the viscoelastic processes, but also increased their intensity.

Related Topics
Physical Sciences and Engineering Chemical Engineering Fluid Flow and Transfer Processes
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