Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
67356 | Journal of Molecular Catalysis A: Chemical | 2008 | 9 Pages |
Abstract
New chiral oxazoline-based ruthenium(II) complexes have been synthetized and fully characterised. The corresponding grafted catalysts were prepared by anchoring the complexes onto SiO2 or Pd/SiO2 supports. 13C CP-MAS NMR and XPS spectroscopies showed that the organometallic complexes remained unchanged when they were deposited on the support. High activity and enantioselectivity in the reduction of acetophenone were achieved with some homogeneous complexes.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Nathalie Debono, Catherine Pinel, Rabih Jahjah, Ali Alaaeddine, Pierre Delichère, Frédéric Lefebvre, Laurent Djakovitch,