Article ID Journal Published Year Pages File Type
674208 Thermochimica Acta 2012 5 Pages PDF
Abstract

The effects of thermal aging at a constant temperature above Af (austenite phase finish temperature) on the martensitic transformation of the CuAlNi shape memory alloy were investigated. The evolution of the transformation temperatures was studied by differential scanning calorimetry (DSC). It was found that the thermal aging at a constant temperature above Af has a complex effect on the transformation parameters of the CuAlNi shape memory alloy. The Ms, Mf, As, and Af transformation temperatures were shifted by the thermal annealing. The thermodynamic parameters such as Gibbs free energy and the elastic strain energy of the alloy experienced a decreasing tendency with increasing the aging time. The structural properties of aged alloy samples were studied by X-ray diffraction measurements at room temperature. It was found that the phase transformation parameters of the alloy are controlled by the crystallite size effect.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The evolution of transformation temperatures was studied by DSC. ► The thermal aging has a prominent effect on the transformation parameters. ► The martensite decomposition reaction did not occur on structure and 18R martensite of structure.

Related Topics
Physical Sciences and Engineering Chemical Engineering Fluid Flow and Transfer Processes
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