Volumetric properties of binary and ternary mixtures of bis(2-hydroxyethyl)amine with water, methanol, ethanol from (278.15 to 353.15) K

Densities of the binary and ternary systems formed by mixtures of bis(2-hydroxyethyl)amine (DEA) + water, DEA + methanol (MeOH), DEA + ethanol (EtOH) and DEA + MeOH + water, DEA + EtOH + water were measured at atmospheric pressure for the whole composition range at temperatures from 278.15 K to 353.15 K using an Anton Paar digital vibrating U-tube densimeter (model DMA 5000M). The excess molar volumes have been calculated from the experimental densities in this work and correlated using the Redlich–Kister equation. A set of parameters for the Redlich–Kister equation has been determined to represent the density of the liquid mixture.

► Volumetric properties of binary and ternary mixtures of bis(2-hydroxyethyl)amine with water, methanol, ethanol were studied. ► The excess molar volumes have been correlated using the Redlich–Kister equation. ► A set of parameters for the Redlich–Kister equation has been determined.