Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
674766 | Thermochimica Acta | 2010 | 6 Pages |
Abstract
The overall model of the form: dα/dt = (K′ + Kαm)(1 − α)n, known as Kamal's model, has been analysed in this work. Although it can describe well the isothermal DSC experiment, the statistical criteria does not allow fixing exactly the adjustable power exponents in the model. In turn, the overall “reaction order” varies in a large range at almost identical confidence limits. The model evaluated in isothermal DSC mode at different values of m and n has been tested. The test has not been found out reliable to describe the data at varying temperature.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Valery L. Zvetkov, Rumen K. Krastev, Senen Paz-Abuin,