| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67529 | Journal of Molecular Catalysis A: Chemical | 2007 | 5 Pages |
The first direct organocatalytic system for oxidizing alcohols to aldehydes with molecular oxygen is described. The catalytic activity of 9,10-diaminophenanthrene with and without the presence of transition metals was studied in the oxidation of benzylic alcohols to corresponding aldehydes. The catalytic reaction occurs at elevated dioxygen pressure and temperature in alkaline aqueous solutions. Up to 80% conversions were observed in organocatalytic oxidation of 3,4-dimethoxybenzyl alcohol to corresponding aldehydes. Addition of transition metal ions to reaction solution increased the catalytic activity significantly. Complete conversions of 3,4-dimethoxybenzyl alcohol to aldehydes were observed in the presence of copper and iron ions.
Graphical abstractThe first direct oxidation of benzylic alcohols to aldehydes with a 9,10-diaminophenanthrene organocatalyst using molecular oxygen as terminal oxidant is described. Transition metal ions increase the catalytic activity of the reaction significantly. Up to 80% conversion from alcohol to aldehyde were observed in organocatalytic reaction and complete conversions in the presence of iron and copper ions. Figure optionsDownload full-size imageDownload as PowerPoint slide
