Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
675464 | Thermochimica Acta | 2007 | 5 Pages |
Abstract
Fourteen rare earth complexes with salicylic acid RE(HSal)3·nH2O (HSal = C7H5O3; RE = La–Sm, n = 2; RE = Eu–Lu, n = 1) were synthesized and characterized by elemental analysis, and their thermal decomposition mechanism were studied with TG–DTG technology. The constant-volume combustion energies of complexes, ΔcU, were determined by a precise rotating-bomb calorimeter at 298.15 K. Their standard molar enthalpies of combustion, ΔcHm∘, and standard molar enthalpies of formation, ΔfHm°, were calculated.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Xu-Wu Yang, Wu-Juan Sun, Cong-Yu Ke, Hang-Guo Zhang, Xiao-Yan Wang, Sheng-Li Gao,