| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67640 | Journal of Molecular Catalysis A: Chemical | 2007 | 5 Pages |
The oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn(salen) complex (R,R)-1 with good to excellent ee's in water in the presence of diacetoxyiodobenzene (PhI(OAc)2) is described. The resin supported (R,R)-1 was recovered quantitatively by simple filtration and reused for three times with consistent activity.
Graphical abstractThe oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn(salen) complex (R,R)-1 with good to excellent ee's in water in the presence of diacetoxyiodobenzene (PhI(OAc)2) is described. The resin supported (R,R)-1 was recovered quantitatively by simple filtration and reused for three times with consistent activity.Figure optionsDownload full-size imageDownload as PowerPoint slide
