| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67648 | Journal of Molecular Catalysis A: Chemical | 2007 | 4 Pages |
Palladium(II) perfluorooctanesulfonate [Pd(OSO2Rf8)2] catalyses the highly efficient Heck reaction in the presence of a catalytic amount of a perfluoroalkylated-pyridine as a ligand in a fluorous biphase system (FBS) composed of toluene and perfluorodecalin. The fluorous phase containing the active palladium species is easily separated and can be reused several times without a significant loss of catalytic activity.
Graphical abstractPalladium(II) perfluorooctanesulfonate [Pd(OSO2Rf8)2] catalyses the highly efficient Heck reaction in the presence of a catalytic amount of a perfluoroalkylated-pyridine as a ligand in a fluorous biphase system composed of toluene and perfluorodecalin. The fluorous phase containing the active palladium species is easily separated and can be reused several times without a significant loss of catalytic activity. Figure optionsDownload full-size imageDownload as PowerPoint slide
