Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
67658 | Journal of Molecular Catalysis A: Chemical | 2007 | 7 Pages |
Abstract
The oxidative kinetic resolution of racemic secondary alcohols was efficiently catalyzed by chiral dimeric Mn(III) salen complexes using PhI(OAc)2 as an oxidant in the presence of various additives in water/organic solvent mixture. Excellent ee (up to 99%) of chiral secondary alcohols was achieved in 0.5 h. The catalyst 1A was recovered easily and reused five times with retention of enantioselectivity.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Kavita Pathak, Irshad Ahmad, Sayed H.R. Abdi, Rukhsana I. Kureshy, Noor-ul H. Khan, Raksh V. Jasra,