| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67783 | Journal of Molecular Catalysis A: Chemical | 2007 | 7 Pages |
Abstract
A first example of a highly stable benzimidazole N-donor dinuclear palladacycle complex is reported. X-ray diffraction analysis showed that two ligands assembled through complexation to two palladium(II) ions to give a compressed rectangular shaped metallamacrocycle. This complex catalyzed Suzuki coupling reaction effectively in MeOH at room temperature. Hg(0) poisoning test supports the formation of L-Pd(0) species in the catalytic reaction.
Graphical abstractA first example of a highly stable benzimidazole N-donor dinuclear palladacycle complex is reported. The complex catalyzed biaryl formation reaction effectively in MeOH at room temperature. Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Sachindranath Pal, Wen-Shu Hwang, Ivan J.B. Lin, Chen-Shiang Lee,