| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67913 | Journal of Molecular Catalysis A: Chemical | 2008 | 6 Pages |
Abstract
New highly active heterogeneous silicaethylphosphatrioxaadamantane palladium catalysts with very low millimole per gram palladium load are reported. Applied to a broad range of Suzuki substrate pairs in 0.1–0.2 mol%, these catalysts are very effective, reusable and resistant to leaching for reactions in hot xylene or with microwave irradiation of EtOH:H2O:DME solutions.
Graphical abstractWe report on the immobilisation of the phosphaadamantane function onto silica via an ethyl linker group and the development of heterogeneous catalysts for use in Pd-catalysed Suzuki couplings.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Meritxell Guinó, Alice C. Sullivan, John R.H. Wilson,