| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 67939 | Journal of Molecular Catalysis A: Chemical | 2007 | 5 Pages |
MCM-41-supported bidentate phosphine palladium(0) complex was conveniently synthesized from commercially available and cheap γ-aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydrate. The powder X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were employed to characterize the title palladium complex. It was found that this complex is a highly active catalyst for the heterogeneous Suzuki reaction of aryl halides with arylboronic acids and can be reused many times without loss of activity.
Graphical abstractMCM-41-supported bidentate phosphine palladium(0) complex [MCM-41-2P-Pd(0)] was conveniently synthesized from commercially available and cheap γ-aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydrate. This complex is a highly active catalyst for the heterogeneous Suzuki reaction and can be reused many times without loss of activity.Figure optionsDownload full-size imageDownload as PowerPoint slide
