Purification of xylose in simulated hemicellulosic hydrolysates using a two-step emulsion liquid membrane process

•Xylose was purified from simulated hydrolysates through a two-step ELM process.•Acetic acid or sulfuric acid was selectively removed and enriched in each ELM step.•Sugar purification through the two-step ELM process seemed economically feasible.

Purification of xylose in simulated hemicellulosic hydrolysates was attempted using a two-step emulsion liquid membrane (ELM) process. The effects of various experimental variables on extraction of each component in the hydrolysates were investigated in the ELM steps. In the first ELM step, acetic acid could be selectively removed from the hydrolysates and highly enriched in the stripping phase, and loss of xylose was insignificant. In the second ELM step, sulfuric acid could be selectively removed from simulated acetic acid-free hemicellulosic hydrolysates and somewhat enriched in the stripping phase. There was just small loss of xylose, and the final pH of the feed phase approached a pH level suitable for ethanol fermentation. Also, concentration of xylose in the feed phase was attained as an incidental outcome during each ELM run. Conclusively, the two-step ELM process was found to be a promising futuristic technology for purification of sugars in real hemicellulosic hydrolysates.