Integration of a kraft pulping mill into a forest biorefinery: Pre-extraction of hemicellulose by steam explosion versus steam treatment

•Steam explosion and steam pre-treatments were carried out before kraft pulping.•The rate of extraction of hemicelluloses was similar with both pre-treatments.•Steam explosion enhanced delignification more efficiently.•Pre-treatments reduced paper mechanical properties owing to the fiber morphology.•Paper optical properties were boosted when pre-treatments were carried out.

Growing interest in alternative and renewable energy sources has brought increasing attention to the integration of a pulp mill into a forest biorefinery, where other products could be produced in addition to pulp. To achieve this goal, hemicelluloses were extracted, either by steam explosion or by steam treatment, from Eucalyptus globulus wood prior to pulping. The effects of both pre-treatments in the subsequent kraft pulping and paper strength were evaluated. Results showed a similar degree of hemicelluloses extraction with both options (32–67% of pentosans), which increased with the severity of the conditions applied. Although both pre-treatments increased delignification during pulping, steam explosion was significantly better: 12.9 kappa number vs 22.6 for similar steam unexploded pulps and 40.7 for control pulp. Finally, similar reductions in paper strength were found regardless of the type of treatment and conditions assayed, which is attributed to the increase of curled and kinked fibers.