Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
682596 | Bioresource Technology | 2010 | 7 Pages |
Abstract
Electro-Fenton denitrification of a model wastewater was studied using platinised titanium electrodes in a batch electrochemical reactor. The model wastewater was prepared from components based on the real aquaculture effluent with nitrate concentrations varying from 200 to 800 mg Lâ1. The technical as well as scientific feasibility of the method was assessed by the relationship between the most significant process variables such as various Fenton's reagent to hydrogen peroxide ratios (1:5; 1:20 and 1:50) and current densities (0.17 mA cmâ2, 0.34 mA cmâ2 and 0.69 mA cmâ2) and their response on denitrification efficiency in terms of nitrate degradation using central composite Box-Behnken experimental design was determined. The goodness of the model was checked by the coefficient of determination R2 (0.9775), the corresponding analysis of variance P > F and a parity plot. The ANOVA results indicated that the proposed model was significant and therefore can be used to optimize denitrification of a model wastewater. The optimum reaction conditions were found to be 1:20 Fenton's reagent/hydrogen peroxide ratio, 400 mg Lâ1 initial nitrate concentration and 0.34 mA cmâ2 current density. Treatment costs in terms of electricity expenditure at 0.17, 0.34 and 0.69 mA cmâ2 was 7.6, 16 and 41.8 â¬, respectively, per kilogram of nitrates and 1, 2 and 4 â¬, respectively, per cubic meter of wastewater.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Process Chemistry and Technology
Authors
Jurate Virkutyte, Ekaterina Rokhina, Veeriah Jegatheesan,