| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 68281 | Journal of Molecular Catalysis A: Chemical | 2008 | 5 Pages |
Esterification of acetic acid with 1-octanol was studied using a series of alkylammonium salts as Brønsted acidic ionic liquids. The following ionic liquids were prepared and used as catalysts and mediums in the esterification reaction; [Et3NH][HSO4], [Et3NH][H2PO4], [Et3NH][BF4], [Et3NH][p-CH3C6H4SO3], [Et2(PhCH2)NH][HSO4], [n-Bu3NH][HSO4], [n-Oct3NH][HSO4], [Et2NH2][HSO4], [Et2NH2][H2PO4], [Et2NH2][BF4], [i-Pr2NH2][HSO4], [EtNH3][HSO4], [EtNH3][H2PO4], and [EtNH3][BF4]. Higher acidity of the anion in the ionic liquid resulted in high yield of the ester. Yield of the ester decreased with increase in the size of the cation. There was no phase separation in the reactions where size of anion and/or cation was bigger.
Graphical abstractA series of ionic liquids based on alkylammonium salts were synthesized. The ionic liquids were used as catalysts and mediums for the esterification of acetic acid with 1-octanol as a probe to understand their structure–activity relationship in the Fisher esterification.Figure optionsDownload full-size imageDownload as PowerPoint slide
