Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
68496 | Journal of Molecular Catalysis A: Chemical | 2006 | 9 Pages |
Abstract
An overview is presented on the performance of Pd-complexes with phenanthroline-type ligands that are highly active catalysts for alcohol oxidation in water as well as in water/polar co-solvent mixtures. The mechanistic details of this intriguingly active and stable Pd-species are summarized. The (neocuproine)Pd(OAc)2 catalyst is unique in that it tolerates water, polar co-solvents and a wide variety of functional groups in the alcohol. Turnover frequencies of >1500 h−1 were achieved in the latter case and a series of alcohols was oxidized with 0.1–0.5 mol% of catalyst.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Isabel W.C.E. Arends, Gerd-Jan ten Brink, Roger A. Sheldon,