Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
68515 | Journal of Molecular Catalysis A: Chemical | 2008 | 7 Pages |
Synthetic talc (magnesium organo silicates; MOS) was synthesized by sol–gel method under non-hydrothermal conditions and modified by introducing amine/diamine functionalities in the interlayer space. The applicability of amine/diamine functionalized MOS was studied as catalysts for the synthesis of jasminaldehyde or α-pentylcinnamaldehyde by condensation of 1-heptanal with benzaldehyde. The effect of amine/diamine functionality, amount of catalyst, benzaldehyde to 1-heptanal molar ratio and temperature on the selectivity of jasminaldehyde was studied in detail. The highest conversion of 1-heptanal (99%) with 82% selectivity of jasminaldehyde was achieved using MOS3 as a catalyst. The rate constant for condensation of 1-heptanal with benzaldehyde was calculated under optimized reaction conditions. This is the first report on application of MOS as a solid base catalyst for the condensation of 1-heptanal with benzaldehyde.
Graphical abstractThe amine/diamine functionalized synthetic talc (magnesium organo silicates; MOS) was synthesized by sol–gel method under non-hydrothermal conditions and used as a solid base catalyst for synthesis of jasminaldehyde. The highest conversion of 1-heptanal (99%) with 82% selectivity of jasminaldehyde was achieved using MOS3 as a catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide