| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 68556 | Journal of Molecular Catalysis A: Chemical | 2006 | 5 Pages |
Abstract
V-K10 presents both monomeric and dimeric species, that can be reversibly transformed between V4+ and V5+ states. The species in the highest oxidation state were found to be the catalytic sites for sulfide oxidation with tert-butylhydroperoxide (TBHP), affording excellent sulfoxide selectivity. With chiral modifiers, V-K10 leads to enantioselectivities in the range of 9-11% ee.
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Physical Sciences and Engineering
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Authors
I. Khedher, A. Ghorbel, J.M. Fraile, J.A. Mayoral,