Influence of dimethyl formamide pulping of bagasse on pulp properties

Organosolv pulping of bagasse was conducted following a central composite design using a two-level factorial plan involving three pulping variables (temperature: 190–210 °C, time: 120–180 min, organic solvent charge: 40–60% dimethyl formamide). Responses of pulp properties (yield and holocellulose, α-cellulose, kappa number, ash and ethanol–dichloromethane extractives contents) and the pH of the resulting wastewater to the process variables were analyzed using statistical software (MINITAB). Main factor analysis revealed that optimum pulp has the following characteristics: 82.7% (yield), 92.9 (kappa number), 95.84% (holocellulose), 83.53% (α-cellulose), 1.403% (ash), 2.562% (ethanol–dichloromethane extractives contents) and 6.39 (pH). These results showed that acceptable properties of pulps could be gained at 200–210 °C for 150 min and 40–60% DMF. Based on these results, this method could be used for pulping of bagasse equivalent NSSC concerning high yield at a fixed kappa number. In addition, bagasse could be pulped with ease to approximately 55% yield with a kappa number approximately 31. Numerical analyses showed that cooking temperature had the greatest influence on properties of obtained pulps within the DMF concentrations and cooking time as cooking variables.