| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 68748 | Journal of Molecular Catalysis A: Chemical | 2006 | 6 Pages |
Abstract
Cross-metathesis of 4-chlorostyrene with vinylsilanes in the presence of second generation of Grubbs catalyst [Cl2(PCy3)(IMesH2)Ru(CHPh)] or silylative coupling in the presence of [RuH(Cl)(CO)(PPh3)3] followed by palladium-catalysed Hiyama coupling have been proved convenient and effective methods for stereoselective synthesis of unsymmetrical stilbenoids.
Graphical abstractHighly effective new tandem reactions: cross-metathesis–Hiyama coupling (CM–HC) and silylative coupling–Hiyama coupling (SC–HC) lead to stereoselective synthesis of unsymmetrical stilbenoids.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Wiesław Prukała, Mariusz Majchrzak, Cezary Pietraszuk, Bogdan Marciniec,