The sulfonic acid-functionalized ionic liquids with pyridinium cations: Acidities and their acidity–catalytic activity relationships

The Brønsted acidities of sulfonic acid-functionalized ionic liquids (SFILs) with pyridinium cations were investigated. The Hammett function values of SFILs are between −1.5 and −3.6 at 110 °C. The acidities of SFILs depend on the anions, and have the order as follows: [PSPy][BF4] > [PSPy][HSO4] > [PSPy][pTSA] > [PSPy][H2PO4] ([PSPy] = N-propane–sulfonic acid pyridinium). The acidity order of SFILs is consistent with their activity order observed in some acid-catalyzed reactions. The minimum-energy geometries of SFILs manifest that anions have strong interactions with the sulfonic acid proton. It is considered that in addition to the alkyl sulfonic acid group, the anion is likely to serve as available acid sites. Hence the acidities and catalytic activities of SFILs depend on the kinds of anions.

Graphical abstractThe acidities and catalytic activities of sulfonic acid-functionalized ionic liquids with pyridinium cations depend on the kinds of anions. The minimum-energy geometries of SFILs manifest that the anions have strong interactions with the sulfonic acid proton. It is considered that in addition to the alkyl sulfonic acid group, the anion is likely to serve as available acid sites. Hence the acidities and catalytic activities of SFILs depend on the kinds of anions.Figure optionsDownload full-size imageDownload as PowerPoint slide