| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 68826 | Journal of Molecular Catalysis A: Chemical | 2007 | 9 Pages |
Abstract
The palladium(0)-catalyzed annulation of catechol with propargylic carbonates bearing different functionalized groups (hydroxy, tert-butyldimethylsilyloxy, ester, diethylamino) afforded functionalized 2,3-dihydro-2-ylidene-1,4-benzodioxin isomers. The regioselectivity of the cyclization depends strongly on the nature of the substituent and on the chain length between the triple bond and the function.
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Norbert Dominczak, Paul Lhoste, Boguslaw Kryczka, Denis Sinou,