Article ID Journal Published Year Pages File Type
68853 Journal of Molecular Catalysis A: Chemical 2007 5 Pages PDF
Abstract

The addition of acetanilides to ethyl propiolate proceeds under neutral conditions in the presence of triphenylphosphine to give the corresponding α-substituted alkyl acrylates together with variable amounts of the β-substituted isomer with (E) geometry. Addition of arylsulfonylanilides to alkyl propiolates under similar conditions, produced only the alkyl (E)-3-arylsulfonylanilino-2-propenoates.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Authors
, , , ,